We present the in-depth determination of the magnetic properties and electronic structure of the luminescent and volatile dysprosium-based single molecule magnet [Dy2(bpm)(fod)6] (Hfod = 6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedione, bpm = 2,2′-bipyrimidine). Corresponding authors, a Please check your email for instructions on resetting your password. 1H‐ und 13C‐NMR, IR und analytische Daten belegen, daß diese Cobalt(III)‐Komplexe zweikernig sind. Department of Chemistry The University of Kansas Malott Hall Lawrence, KS 66045–0046/U.S.A. The 1H and 13C‐NMR, IR and elemental analysis data indicated that the cobalt(III) complexes are dinuclear. and you may need to create a new Wiley Online Library account. You do not have JavaScript enabled. 31,34 Fetching data from CrossRef. Department of Chemistry, University of Copenhagen, Universitetsparken 5, Denmark. Laboratoire National des Champs Magnétiques Intenses (LNCMI-EMFL), CNRS, UGA, 38042 Grenoble, France, e Ab initio calculations were used to obtain a global picture of the electronic structure and to predict possible single molecule magnet behaviour, confirmed by experiments. The orientation of the susceptibility tensor was determined by means of cantilever torque magnetometry. Abstract The first triply bridged dinuclear platinum(III) compound with acetamidate ligands, X[Pt2Cl4{N(H)C(CH3)O}3] (X = K+ or AsPh4+), has been isolated in … 3.0 Unported Licence. The First Example of Dinuclear Co(III) Complexes Containing Crown Ether Moieties Assoc. Reproduced material should be attributed as follows: Information about reproducing material from RSC articles with different licences is available on our Permission Requests page. Enter your email address below and we will send you your username, If the address matches an existing account you will receive an email with instructions to retrieve your username, By continuing to browse this site, you agree to its use of cookies as described in our, I have read and accept the Wiley Online Library Terms and Conditions of Use. This may take some time to load. Neue zweikernige, oktaedrische Cobalt(III)‐Komplexe wurden dargestellt und ihre Eignung zur Reaktion mit 4,4′‐Trimethylendipyridin untersucht. Unlimited viewing of the article/chapter PDF and any associated supplements and figures. 3.0 Unported Licence. An experimental determination of the electronic structure of the lanthanide ion was obtained combining Luminescence, Far Infrared and Magnetic Circular Dichroism spectroscopies. a dinuclear system occurs at the stage of projectile capture by the target nucleus, whereupon the din-uclear system evolves toward a compound nucleus via nucleon transfer from the lighter to the heavier nucleus. Use the link below to share a full-text version of this article with your friends and colleagues. 29–34 The latter are especially attractive, because the magnetic properties may be switched (electro)chemically by reducing and oxidizing the bridging ligand. to access the full features of the site or access our, All publication charges for this article have been paid for by the Royal Society of Chemistry. Unlimited viewing of the article PDF and any associated supplements and figures. The dinuclear metallocene compound according to the present invention is a dinuclear metallocene compound with a new structure, and, unlike a single-site catalyst, has high accessibility to a substrate, …